Leading man Daniel Craig was supported by wife Rachel Weisz
The three Bond ladies - Monica Belluci, Naomie Harris and Lea Seydoux - all looked equally incredible at the event.
Monica Belluci, just how do you look like this at 50?
Naomie Harris showed off her beautiful skin in this bright orange maxi
Lea literally dazzled on the red carpet on Monday evening
Susanna Reid looked beautiful in her pale blue dress with diamante and fur details.
Ronan Keating also hit the red carpet with his wife, Storm
Dancing veteran Darcey Bussell accessorised her hot pink gown with a leather jacket and wet look clutch
The Duchess of Cambridge showed off her slim frame in this delicate number