Rumours of trouble in their marriage have been around for a while, but Nick, 33, seemed to confirm this last month when he suggested to reporters that there was 'trouble in paradise'.
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A source told E!: "Mariah has started the divorce process. She's getting all her ducks in a row."
Meanwhile, presenter Nick has taken to Twitter to deny making the comments about his marriage to the 44-year-old singer.
He said: "'Trouble in Paradise' is the dumbest phrase I've ever heard! I would never say that s***.
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"I will always lover her unconditionally for this and so much more. @MariahCarey is an amazing mother and I trust her wholeheartedly…"
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Nick added: "For the record I NEVER have, nor will I make a statement regarding my marriage", before saying: "I love @MariahCarey and that will never change!!!"
So far Mariah hasn't commented on the rumours that she and Nick are divorcing, with her publicist saying: "Mariah is focusing on her children and her upcoming tour."